Liverpool will play Chelsea in the first all-English UEFA Super Cup on 14 August in Istanbul.
The Blues booking their place with a 4-1 win over Arsenal in the Europa League on Wednesday. The Reds claimed Champions League trophy for the sixth time with a 2-0 victory over Tottenham in Madrid.
Liverpool are the last English side to win the Super Cup, back in 2005.
Jurgen Klopp's Liverpool will be in seven competitions next season.
After winning the Champions League, they will be the European representatives in the Club World Cup in December, with the hosts to be decided at a Fifa meeting on Monday.